System for gas sparging into liquid

ABSTRACT

A SYSTEM FOR SPARGING GAS INTO LIQUID AS FOR EXAMPLE OXYGEN INTO WASTE LIQUID CONTAINING ORGANIC SOLIDS, WHEREIN THE GAS IS INJECTED WITH A VERTICAL DIRECTION COMPONENT AS A MULTIPLICITY OF DISCRETE STREAMS ORBITED AROUND A COMMON VERTICAL AXIS TO SCRIBE A MULTIPLICITY OF CIRCLES HAVING DIFFERENT RADII, AND THROUGH SMALL OPENINGS TO FORM SMALL GAS BUBBLES.

NOV- 27 1973 J. R. MCWHIRTER ETAL 3,775,307

SYSTEM FOR GAS SPARGNG `[NTO LIQUID 6 Sheets-Sheet Filed April 8, 1971 [I o 76A mumumn...

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ATTORNEY Nov. 27, 1973 J. R. McwHlRTER ETAL 3375,30?

l SYSTEM FOR GAS SPARGING INTO LIQUID Filed April s, 1971 e sheets-sheet 2 Vf 3 Q: IV f Vf d INVENTORS JON G. ALBERTSSON JOHN R.Mc WHIRTER ATTO RNEY Nov. 27, 1973 J. R. McwHmTER ETAL Y 3,775,30?y

SYSTEM FOR GAS SPARGTNG INTO LIQUID Filed April 8, 1971 6 Sheets-Sheet 3 INVENTORS JON G. ALBERTSSON Y.IOHN R. MCWHIRTER ATTORNEY Nov. 27, 1973 L R, McwHlRTER ETAL 3,775,307

SYSTEM FOR GAS SPARGING INT0 LIQUID 6 Sheets-Sheet 4 Filed April S, 1971 md No .omo 6.o O

ma mm mm om Om ON. C@ Om Ov Om ON or m N to @o @o INVENTORS JON G. ALBERTSSON JOHN R.

MCWHIRTER ATTORNEY Nov.` 27, 1973 J. R, MowHlR'reR ETAL 3,775,307

SYSTEM FOR GAS SPARGING INTO LIQUID Filed April e, 1971 O e sheets-sheet 5 SURFACE AREA-FTz/FT OF GAS(ACTUAL)` IOO 'O /O 20 30 40 50 60 y 70 FACTOR M2132- W2/SEC2 M@ .ffm

ATTO RN EY Nov. 21, 1973 J, R, MCwHmTER UAL 3,775,301

SYSTEM FOR GAS SPARGING INTO LIQUID Filed April 8, 1971 6 Sheets-Sheet e2 xw wi mm Si 5523? m10 NG SO Zsers/2.1;: zo aN aolovd INVENTORS JON G. ALBERTssoN BYJOHN R. McwHlRTER 9M 1" M ATTORNEY United Seres Pe@ 3,775,307` v y SYSTEM FOR GASSPARGING INTO LIQUID John R. McWhirter, Westport, Conn., and Jon G. Albertsson, Grand Island,` N.Y., assignors to Union Carbide Corporation, NewYork, N.Y. Continuation-impart of abandoned application Ser. AN 32,070, Apr. 27, 1970. This application Apr. 8, 1971, Ser. No. 132,483 s Int. Cl. C02c 1/12 U.S. Cl. 210-14 16 Claims ABSTRACT oF THE DISCLOSURE A system for sparging gas into liquid as for example oxygen into waste liquid containing organic solids, Wherein the gas is injected with Aa vertical direction component as a multiplicity of discrete streams orbited around a common vertical axis to scribe a multiplicity of circles having different radii, and through small openings to form small gas bubbles.

CROSS REFERENCE TO RELATED APPLICATIONS This application is a continuation-impart of Ser. No. 32,070 led Apr. 27, 1970, in the names of Jon R. Albertsson and John R. McWhirter, and now abandoned.

BACKGROUND OF THE INVENTION This invention relates to a method of and apparatus for sparging gas into liquid in the form of small bubbles.

Mass transfer processes between gases and liquids are commonly carried out by producing bubbles of the gas in the liquid. Mass transfer occurs at the gas-liquid interfaces generated in the two-phase system, and the greater the interfacial area, the faster and more eiiiciently the process proceeds.

The efficiency of such aeration processes is greatly improved if the gas can be introduced into the liquid as tiny bubbles on the order of `0.040.l6 inches in diameter. For example, comparing bubbles of 0.1 and 0.24 inches average diameters, the gas-liquid interfacial surface area produced by one cubic foot of gas is about 720 sq. ft. and 300 sq. ft., respectively. The production of small bubbles with large area increases the rate of mass exchange between the gas and the liquid. In gravity systems, it also slows the rate of bubble rise due to buoyancy and hence increases the time available for mass transfer. Once formed in the mixed liquor, tiny bubbles show less tendency to coalesce th'an do larger bubbles, and therefore, the area advantage of small bubbles is even greater in practice than indicated by the initial bubble size.

When a small volume of gas is to be introduced into a large volume of liquid, a sparging system is often used. By providing tiny orifices in the sparger, or fabricating the sparger of a porous metal, very small bubbles can be produced with a large gas-liquid intertacial area. Such spargers are commonly located at the bottom of a tank so that the bubbles rise slowly through the liquid. In large tanks, the sparger in the form of a long perforated pipe can be rotated slowly in a horizontal plane and thereby release a moving cloud of bubbles throughout the entire body of liquid.

Some aeration processes involve liquids containing sus-y maintain. Oriiices (openings) can'be operated success-- fully in such mixed liquors if they are relatively large in diameter, e.g.,l 1A; inch or above. However, it is well known that bubbles produced from submerged openings will grow 3,775,307 Patented Nev. 27, 1973 to a size ymuch larger than the openings before breaking away.A Thus, the smallest average-sized bubbles which can be produced by prior art sparging systems from aV practically-sized, V1 inch opening, are at least A inch in diameter and afforded less than300 sq. ft. gasliquid interfacial area per cu. ft. of gas. f Y

Non-limiting examples of mass transfer process involving suspended solids are fermentation processes and the activated sludge process for waste disposal. The present invention is especially advantageous for use in an activated sludge process wherein gaseous oxygen is dissolved in waste liquids containing organic solids. The beneiits of small bubbles and rapid, efficient oxygen solution are very important when the oxygen-source gas is high in oxygen content or is pure oxygen. With the conventional air aeration of waste liquor, the source gas is available at the cost of its compression only. However, an oxygen-enriched source gas has a higher value, and must be elfectively utilized in the activated sludge process for replacement of air.

The activated sludge process can benefit from easier, faster solution of oxygen from the source gas in one or more of the following ways:

(1) More complete utilization of the oxygen available in the source gas.

(2) Reduced power costs for compression of the source gas.

(3) Reduced power costs for agitation of the mixed liquor.

(4) Higher dissolved oxygen content of the mixed liquor.

(5) Reduced retention time of mixed liquor inthe aeration basins.

An object of this invention is to provide an improved method of and apparatus for sparging gas into liquid, including mixed liquor.

Another object is to provide such method and apparatus in which the gas is injected into the liquid through openings sufficiently large to avoid clogging thereof, yet form gas bubbles in the bulk liquid which are no longer than the openings and which are uniform in size.

Still another object is to provide such method and apparatus for sparging oxygen gas into waste liquor and sludge.

Other objects and advantages on this invention will be apparent form the ensuing disclosure and appended claims.

SUMMARY second and at volumetric ilow'rate of at least 0-.06 actual 'cubic feet per second per square foot of horizontal area in a spargng zone as gas bubbles in direction having at least a vertical component. The gas streams are simultaneously orbited at tangential velocity of 4.5-33

-feet per rsecond and at rate such that the factor N2D2 is atleast 15 feet2 per second2 about a common vertical axis so as to scribe a multiplicity of circles each perpendicular to the vertical axis but at different radii with all such circles when projected on the horizontal plane falling 1 within a swept area bounded by the circles of minimum andmaximum radii. It should be understood that all such circles may in fact be in the horizontal plane so that such projection would not be necessary. v

`This method includesY a relationship of the total crossysectional areaof the'gas streamsto the aforementioned swept area. In particular, the ratio of total cross-sectional area of the gas streams to the swept area is 0.006-0.06.

Also according to the method, the liquid is flowed at lineal velocity of at least 2 feet per second downwardly through the sparging zone for gas injection therein, and the downwardly flowing gas bubble-containing liquid is discharged from the lower end of the sparging zone.

In the apparatus aspect of the invention, a vertically oriented rotatable shaft is provided having a passageway therein joined at its upper end to pressurized gas supply means. An axial liow impeller is fixedly attached to the rotatable shaft with outwardly extending blades intermediate the shaft upper end and lower end and being aligned to flow liquid downwardly.

A multiplicity of gas sparging arms are also ixedly attached to the rotatable shaft at its lower end. Each arm extends radially outwardly from and the arms are spaced around the shaft with an interior passageway communieating with the rotatable shaft passageway and multiplicity of %,2% inch effective diameter openings spaced from each other along the arm length with the center axis of said openings having a vertical direction component. The diameter scribed by the arm tips is 0.8-1.1 times the diameter scribed by the impeller blade tips. In a preferred embodiment without shrouding, the horizontal center plane of the sparging arms is positioned beneath the impeller horizontal center plane no more than a distance equal to the impeller blade tip scribed diameter. The gas sparging arms and injection openings are arranged so as to scribe a multiplicity of circles each perpendicular to the rotatable shaft but at different radii with all such circles when projected on the horizontal plane falling within a swept area bounded by the circles of minimum and maximum radii. As with the method of the invention, gas injection openings may all rotate in the same horizontal plane so that projection thereto is not necessary.

In this apparatus the gas injection openings are also provided in suficient size and number such that the ratio of total cross-sectional area of the openings to the aforementioned swept area is 0.006-0.06. The apparatus also includes a multiplicity of fixed vertical radial batiies at spaced intervals around the lower end of the rotatable shaft to inhibit the tangential movement of liquid in this vicinity lwhich if excessive would otherwise reduce mixing efficiency and mass transfer efficiency of gas thereto.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic view taken in cross-sectional elevation of a ground-positioned system for sparging gas into liquid according to one embodiment of the invention.

FIG. 2 is a plan view looking downwardly on the FIG. 1 system with a portion of the cover being cut away.

FIG. 3 is a plan view of a suitable sparger arm assembly for use with the FIGS. 1-2 system.

FIG. 4 s an elevation view taken along line 4 4 of the FIG. 3 assembly.

FIG. 5 is a schematic view taken in cross-sectional elevation of a floating system for sparging gas into liquid according to another embodiment of the invention.

FIG. 6 is an enlarged end view taken in cross-section of a sparger arm section, also showing the various flow and direction relationships of this invention.

FIG. 7 is a graph illustrating the relation between bubble size distribution and the factor NZD2 representative of energy developed by the sparger in the sparging zone. 1

FIG. 8 is a graph illustrating the relation between gaslquid interfacial surface area/ volume ratio and the factor N2D2; and

FIG. 9 is a graph illustrating the relation between the volumetric ow rate of gas introduction per square unit of sparging zone horizontal area and the factor NZDZ. The relationship is shown parametrically in terms of the downward liquid velocity through the sparging zone.

4 DESCRIPTION OF PREFERRED EMBODIMENTS Referring now to the drawings and in particular FIGS. 1-6, pressurized gas is introduced through conduit 1 to vertically oriented rotatable shaft 2 having passageway 3 therein joined at its upper end to conduit 1. Axial flow impeller means as for example propeller 4 is fixedly attached to shaft 2 intermediate the latters upper end and lower end with outwardly extending blades. A multiplicity of gas sparging arms 5 are fixedly attached to rotatable shaft 2 at its lower end. Each arm extends radially outwardly from the shaft and has an interior passageway 6 communicating with the rotatable shaft passageway 3. Shaft 2 is driven by an appropriate power source as for example motor 7.

A multiplicity of Mig-1A inch effective diameter openings 8 as for example orifices are spaced from each other and preferably at least 2 center-to-center effective diameters along the arm length. 'Ihis spacing is preferred to maintain distinct, separate gas injection streams with characteristically small bubbles which do not combine in the immediate vicinity of the arm to form undesirable large bubbles. As used herein the phrase effective diameter includes non-circular as well as circular openings, and refers to the diameter of the largest circle which can be inscribed within the openings. =For noncircular openings the preferred center-to-center spacing refers to the distance between the closest of such largest circles which can be inscribed in adjacent openings. The center of axes x-x of these openings 8 has a vertical direction component so as to scribe a multiplicity of circles (as for example CI and CH of FIG. 3) each in a plane perpendicular to the rotatable shaft 2. A vertical direction component of the axes is necessary to realize a horizontal shearing action of liquid on the gas bubbles emerging from openings 8 into the liquid, as discussed hereinafter in connection with FIG. 6. When all such circles CI and Cn are projected on the horizontal plane p--p of FIG. 4, they fall within a swept area bounded by the circles of minimum radii rm, and maximum radii rm. It will be noted that the FIGS. 3-4 sparger embodiment has all such circles in the horizontal plane p--p and projection thereto is unnecessary. However, it is contemplated that arms 5 may be positioned inclined from the horizontal with tips either upwardly toward or downwardly away from the axial flow impeller 4, as for example to form a cone-shaped assembly (see dotted lines in FIG. 4). In this event it would be necessary to project rmi and r,Im to the horizontal plane p-p to form the swept area. All arms 5 are preferably in the same horizontal plane p-p of rotation in order to minimize th'e difference in hydrostatic head acting upon the openings 8 within the sparging zone.

Openings 8 are provided in sufficient size and number such that the ratio of their total cross-sectional area to the swept area is 0.006-0.06, preferably with 0.125-20 openings per square inch of swept area. This is, to achieve the improvements of this invention the openings must be provided within certain ranges in terms of total and size. If the total cross-sectional area is less than 0.006 of the swept area, the efficient mass transfer of gas to liquid is limited by insufficient quantity of available gas with respect to the power required to rotate the sparger, and if the ratio exceeds 0.06 the relative quantity of gas is so high that the flowing liquid is unable to effectively sweep the bubbles from the sparging zone rapidly enough to avoid bubble congestion and coalescence into excessively large bubbles, i.e. larger than 1A inch effective diameter. Moreover for a given total gas flow through the sparger, excessive orifice area results in inadequate orifice head loss to avoid weeping into the sparger arms through some of the orifices with consequent partial inactivity of the sparger. Also, an opening total cross-sectional area to swept area ratio above 0.06 may require the openings to be so closely spaced that bubbles emerging from adjacent openings 8 ouv the `same sparger armi 5 may coalesce and become excessively large. 1f fewer` than 0.125 openings'per square inch of 'swept area are provided, the mass transfer ,of gastov liquid is also limited by either insuicient quantity'lof gas with respect to the powerexpendedto lrotate the sparger (at satisfactory gas ilow rates) vor by the 1A' in ch diameter upperlimit onthe openingsize. If there are more than openings per square inch of swept area, the openings are so closely spaced as to result in a degree of bubble coalescense. f

In a preferred embodiment vvof the apparatus from the standpoint of gas-to-liquid mass transfer rate and small bubbles, the openings 8` vare l; inch diamter, the ratio of total cross-sectional area of openings to the swept area is 0.008-0.04 with 1-`4 openings per square inch of swept area. Y

The size and position of the sparger relative to the impeller is important for obtaining high rates of mass transfer. The sparger should j be located substantially within the downward flowing liquid stream from the impeller and relatively near the impeller where liquid velocity is high. Substantially vthe full cross section of the liquid stream should bev used for gas mixing in order "I impellerhorizontal centerplanesfisshownin FIG. l as Table Ilists illustrative sparger embodiments of the invention, each employingeight horizontal arms with l/a inch diameter openings.

' To minimize vortex flowof liquid in the spar'ging zone a multiplicity of vertical baiiles are radially positioned at spaced intervals around the lower end of rotatable shaft 2. These baffles may for example be in the form of narrow radial baflies 9a, 9b and 9c extending from and supported by the inner wall of container 10 (support means not illustrated). These bafes are located at spaced intervals around the shaft 2' perimeter, e.g., 90, and preferably positioned in a spoke-like con-iiguration. As illustrated in FIG. 1, vertical radial narrow baies may be located either slightly below (9a) at the same level (9b) or above the sparger arms 8 (9c). Relatively long vertical baies =12 may be radially positioned around the shaft 2 perimeter, e.g., at 90 intervals using support means well understood to avoid bubble congestion to aid bubble dispersion by those skilled inthe art, as for example, vertical posts 13.

TABLE I ltotatablel axis Distance Impeller to opemng between Open sparger Impeller to center-inches adjacent Swept areal Openings] diameter, diameter, sparger openngs, area, swept in, swept tip to tip to distance, Rmx m. diameters in.2 area area tip, in. tipI in. in. 2. 76 27. 5 (l) 2, 350 0. 013 1. 04 55 56 24 Z13. i 2g. g (l 1, 72 55 52 24 14and 3.

through the bulk liquid and to maximize the concentration gradients for high mass transfer. l

In order that the sparger zone' occupy the full crosssectionalarea of the liquid stream the diameters scribed by the sparger arm tips and the impeller blade tips should be approximately equal. Since the liquid stream may diverge upon leaving thev impeller the sparger diameter may be slightly greater than the impeller diameter, but in any event the scribed diameter ratio, sparger arm tips/impeller bladetips, should not exceed about 1.1. Similarly, the sparger diameter may be slightly less than the impeller diameter without incurring severe detrimental effects due to the aforementioned bubble congestion, poor dispersion and reduced mass transfer. However the scribed diameter ratio, sparger arm tips/impeller blade tips, `should not be less than 0.8 and preferably should not be less than 0.9. v

The divergence of the liquid streams below the impeller is accompanied by a progressive reduction in liquid velocity'at greater distances from the impeller. This divergence isaccentuated when the impeller-sparger as-l sembly is positioned near the bottom of a basin of liquid so as to effectively land suspend solidscontained therein. Reduced liquid lvelocitiesare detrimentalbe-V cause the liquid does not sweep the bubbles as eiectively from the sparging zone and the propeller-sparger system tends to flood.` For this reason when shrouding is not provided around the impeller-spargery assembly, the horizontal center plane of the sparger arms should be positioned beneath the horizontal center planeof the impeller no more than a distance equal to the impeller blade tip scribed diameter and preferably not'exceeding one-half the impeller bladetip scribed diameter.- As Yused herein` the horizontal center plane of theV sparging 'armsis located at and passes through the horizontal centerlineA of the gas passagewayvconne'ctor between the'rotatable shaft mldv the lower'most Spargelarm, Folexamplein 75 be sparged'into the liquid'for strippmg' undesired material 1 These vertical radial baiiies 12 may be employed in combination with or instead of narrow baffles 9 to prevent the liquid from spinning in small transverse circles to form vortexes. If this occurs, the relative velocity between the sparger arms and the liquid would be signiiicantly reduced, thereby undesirably reducing the liquids shearing action on gas bubbles emerging from the openings 8 and reducing the developed turbulence in the wake of the sparger arms. The number and position of vertical radial baffles to eliminate spin-llow of liquid may be empirically determined for each particular configuration, but in general the problem is more severe in relatively small diameter sparging zones, hence more baffles are needed. The baes required by the apparatus of this invention also reduce the tendency towards ooding at high gas iiow rates and at a particular NZD2 factor level (discussed hereinafter in detail) and liquid velocity the batiies increase the maximum allowable gas yliow rate before ooding occurs.

The feed liquid to be sparged with gas may be introduced at any elevation of container 10 through a suitable conduit 14 and is flowed downwardly by impeller 4 to theY sparging zone 15. Gas-containing liquid is discharged l from the lower end of z one 15- and vmay exit through conduit 16 at the lower end of container 10, or alternatively could pass through a passageway near the upper end of container wall, or 'over a Weir. In' general, the liquid t inlets and outlet may be at the same or opposite ends of the storage container 10i but should be transversely spaced from each other for adequate liquid residence time, e.g.

on the order of 30iminutes. t

The portion of sparked gas rising to the liquid surface and disengaging therefromv may be-released to the surpump-11 to gas feed` conduit 1. The gas may for example therefrom. In this event, the disengaged lgas will usually be discharged from the overhead gas space and not recirculated. Y j ,I

FIG. illustrateslloating:V apparatus which could be used forpracticing this sparging method in a naturally occurring large liquid body, e.g. a lagoon. The same num-` bers have been used for identifying elements corresponding to those in the FIGS. 1 2 apparatus. Dome or cover 16 is supported by floats .17, and the required machinery is positioned thereon, e.g. gas recirculation pump 11 and conduit 14,( rotatable shaft 2 with propeller 4 and sparger 5 positioned thereon, and motor 7 for driving shaft 2t. If vertical radial battles were provided, they might be suspended from the dome or supported from the lagoon bottom. The gas supply means fand provision for delivering electric power to the sparger assembly are not shown in the interest of simplicity. The liquid llow is indicated by dashed lines 18 and preferably extends laterally beyond the dome after downward passage through the sparging zone for receiving gas bubbles. The gas bubbles 1-9 ow more directly upward to the liquid body surface due to the upward force of buoyancy. Accordingly the gas bubbles reaching the liquid surface are captured in the overhead space beneath an appropriately sized dome 16 and are recirculated by pump 11.

Referring now in detail to the method of the invention and in particular FIG. 6, the gas streams are injected into liquid in the sparging zone 15 at lineal velocity V1 of at least 5 ft. per second (f.p.s.) in direction having at least a vertical component as for example along the line x-x. Lineal velocities below 5 f.p.s. permit weeping of liquid downwardly through openings 8 into passageway 6. As previously indicated, the gas is introduced at volumetric ow rate of at least 0.06 actual cubic feet per second per square of horizontal area and preferably at least 0.10 ft.3/sec. x ft.2 in the sparging zone. The expression actual cubic feet refers to the gas volume measured under the conditions prevailing in the sparging zone, i.e. adjusting the gas volume at standard temperature and pressure to the temperature and hydrostatic head in the zone. The expression horizontal area refers to the total area inscribed by the rotating sparger arm tips, and exceeds the previously defined swept area. It will be recognized that considerable power is required to achieve the aforementioned liquid shearing and turbulence effects in the sparging zone. Unless the gas is introduced at least at this volumetric zllow rate, there will be insufficient gas available to effectively utilize this power or to realize the high gas-to-liquid mass transfer coeicients possible with the method and apparatus of the invention.

Simultaneously with the aforedescribed lineal velocity V1, the gas streams are orbited at tangential velocity Vt of 4.5-33 feet per second (f.p.s.). The tangential velocity for any particular gas stream may be determined by the formula: (revolutions per second) X (1r) (diameter of circle), and represents the sparger movement in the horizontal plane p-p. With the aforedescribed vertical radial baflies 9a-9c and 12, it may be assumed that the liquid movement in the horizontal plane is substantially zero and constitutes drag, so that the tangential velocity V, is representative of the shearing action of the liquid on the gas bubbles and also representative of the turbulence produced in the liquid by the rotating sparger arm. If the tangential velocity is less than 4.5 f.p.s., insuicient shearing action and turbulence is provided to release the gas bubbles from opening 8 before the bubbles grow excessively large Yand/0r to subdivide any large bubbles which may be formed in the sparging zone. Where Vt is greater than 4.5 f.p.s. the shearing force in effect tears each bubble from the opening 8 mouth long before its growth alone would produceV suicient buoyant force to cause the separation. Moreover the turbulence produced in the wake of the rotating arms reduces any large bubbles to a small size which can exist in stable form in the high liquid shear regime. i

The tangential velocity Vt of the orbiting gas streams should be less than about 33 f.p.s. to avoid the cavitation phenomenon which occurs when the pressure on the trailing side of a spinning rotor arm falls below the vapor pressure of the liquid at that point. The resultant low pressure gas pocketor vacuole produces large bubbles which is contrary to the objectives of this invention. Moreover, bubbles already suspended in the liquid tend to collapse into a zone of cavitation. The threshold velocity for cavitation cannot be theoretically predicted with close accuracy because the onset is dependent upon many other factors in addition to rotor speed, e.g. rotor shape, system pressure and gas lineal velocity. Cavitation-type spargers are well known in the art and literature sources indicate that the rotor speed (at which cavitation occurs) varies considerably for different apparatus.

In the factor N2D2, N is the speed of sparger arm and impeller blade rotation (in revolutions per second), and D is the diameter of the circle which is circumscribed by the tips of the sparger arms (in feet). This factor is representative of the energy developed by the sparger in the sparging zone in the form of turbulence and shear of the liquid acting on the gas bubbles at the orifice mouth openings and in the wake of the rotating arms. Accordingly, the factor NZD2 intluences the size of bubbles discharged from the sparging zone. It has been discovered that with gas |volumetric flow rates above 0.06 actual cubic feet per second/ft.2 horizontal area and to achieve high gas-to-liquid mass transfer rates, the factor N2D2 must be at least l5 ft2/sec?, preferably at least 20 ft2/sec.

Another requirement of this method is flowing the liquid at lineal velocity Vd of at least 2 f.p.s. downwardly through the sparging zone 15 and preferably 3-7 f.p.s. This velocity of at least 2 f.p.s. is needed to sweep the bubbles from the sparging zone immediately after they are formed and detached. Such velocity is also needed when solids are present to maintain a uniform suspension in the liquid. A liquid velocity Vd not greater than 7 f.p.s. is preferred to insure suflicient contact time for efficient gas transfer to the liquid and to avoid unnecessary energy loss by virtue of repeated liquid acceleration and de-l celeration. The liquid lineal velocity Vd of course exceeds the terminal velocity of gas bubbles in liquid, i.e. about 0.8 f.p.s. for l inch diameter bubbles and slightly higher for larger bubbles.

'Ihe liquid lineal velocity may for example be provided by an external pump, but in th'e apparatus of this invention such velocity Vd is provided by axial iiow impeller 4 as for example a propeller. When the liquid contains suspended solids, impeller 4 not only serves to impart the desired downward ow velocity but also serves to mix the liquor so that the solid is substantially uniformly distributed therein. Impeller 4 of course mixes the gas in the liquid. When the impeller serves to keep solids in suspension, the horsepower required for this function is the major part of the total required power input to the rotatable shaft. For example, in an oxygen gas-biological waste water liquor sparging system this requirement is on the order of 0.08 horsepower per 1,000 gallons waste liquor.

In embodiments wherein the rotating impeller 4 and sparging arms 5 are longitudinally surrounded by container walls 10 and the container bottom end, the general llow pattern of the liquid in the sparging zone 15 may be described as a rolling action. After flowing downwardly through zone 15 for admixture with gas bubbles from the rotating sparger arm surfaces, the liquid reaches the container bottom and ows outwardly to the corners and upwardly along the container walls. Impeller 4 then circulates this liquid inwardly and again down over the rotating sparger arms 5 to repeat the bubble sweeping action. The velocity of this rolling action is low as compared to the downow liquid velocity in the sparging zone. In

atraen embodiments lacking container walls and a bottom as for example the FIG. apparatus, this rolling liquid flowQ- pongntydrisxprodued,bywtherliquid i,rripellerjl (located ponent of the relative liquid velocity Vr. The other comabove the sparger arms 5) which pumps liquid downwardly approximately parallel tothe axis ofshaft rotation.

rolling liquidaowisexcessive, then an unnecessarily large quantity of Aliquidjisbeingjpumped with excessive power consumption. .l f

As previously indicated, the ratio of total cross-sectional area., gf.fligrnultnlty.gigas. streams to theiswept areav between rmi and rm, is 0.0060.06 and preferably 0.008- 0.04. A ratio below 0.006 does not provide sufficient gasliquid contact area for high rate mass-transfer or effectively utilize the power consumed in treating liquid shear and turbulence, Vanda ratio above 0.06 places the streams so close together that* initially small bubbles emerging from adjacent openings coalesce into excessively large bubbles. Moreover', an area ratio lgreater than 0.06 does not obtain suicient head loss across the orifices to avoid weeping of liquid into the sparger arm through some of the orifices. Weeping isV particularly detrimental when solids are present in theA liquid, because circulation of liquid-throughthe sparger arm `can be continuous. As the spargerntrurns, cern'triifugal force promotes circulation of liquidifrom orifices near the center of rotation to orifices near the tip'f th'erin."Slidsntering'the sparger arm will accumulate andk eventually vplug the channel through the arm as well as a substantialfnumber'of outer orifices. lso according to this method,0.125-20 gas streams per square inch of swept area arlpr'eferably injected into the downwardly flowing'liquid as; bubbles, and more preferably 144 gasstreams per square inch of swept area. If fewer than 0.125gas`stream's5are provided, insuicient gas is available for-a maximized gas transfer rate to the liquid in view of the 1A inch diameter upper limit. If more than 20 gas streams are used, they are so closely spaced as to producea degree of |bubble coalescense in view of the 0.006 total cross-sectional area/ swept area lower limit. Inl ar preferred method embodiment, oxygen gas is spargedinto waste liquor containing organic solids, comprising the steps of injecting a multiplicity of discrete oxygen gas streams` of l/s inch diameter spaced at 2.5-3.5 center-#tocenter"diameters apart at a gas flow rate of at least 0.1 actual ft.3/sec.-ft. 2 ofuhorizontal area in the spargingnzone` intogwaste liquor as gas bubbles in the vertical direction'andV simultaneously orbiting the gas streams at tangential lvelocity of at least 5 f.p.s. about a common verticalV axis so asi to scribe a multiplicity of circles each perpendicular to the, vertical axis but at different radii with all such circles in the same horizontal plane falling within la swept Vareabounded by the circles of minimum andlmaximum radii,'.the ratio of total crosssectional-area vofthe gas streams tothe swept area being 0.008-0.04 withl-4` gas streamsvper square inch of swept area. The'waste :liquor is owed at lineal velocity of 3-7 feet per second downwardly through the sparging zone for gas injection therein, and the downwardlyfowing gas bubble-containing liquid is discharged from the lower end of the sparging' zone. "i

' It will be noted from FIGS. 4 and 6 that arms 5 are not necessarily transversely oriented horizontally along line p-'p but instead maybe positioned at included angle a to p-.p. 'I'he reason for this transverse inclination is to align the sparger arm outer surface (from which the gas bubbles are discharged) parallel with the resultant direction of the relative liquid flowV V1.. This relationship avoids pumping of the liquid either upwardly or downwardly by the rotating sparger arms,- and thereby minimizes the power required to rotate the spargenAs shown in the vector diagrams, the tangential velocity V, is only one comd Vd. In contrast to FIG. 4,A the FIG. 6 downward velocity component Vd is not vertical and may in practice be inclined due to a horizontal velocity component imparted to the liquid by the impeller.. The vector angle of V,A

is'usually on the order of 5-15 degrees, and the angle va of sparger arm transverse inclination is also preferably in this range.

FIG. 6 also illustrates the preferred Substantially flat cross-section for the sparger arms with the major axis Aum normal to the gas injection opening center axis and at least twice the length of the minor -axis Ami parallel to such gas injection opening. This configuration is preferred to minimize power consumption and stress on the rotating arms. That is, the force imparted by the liquid in resultant direction Vr on the sparger arm is reduced in proportion to the projected area of the arm in the path of this force. This projected area is minimized and in this preferred embodiment is represented by the relatively narrow leading surface of the sparger arm having a height of Ami (the minor axis).

. The advantages of this invention were illustrated in a series of tests employing a sparger imilar to the FIGS. 3-4 embodiment in a system similar to that illustrated in FIG. 1 for introducing oxygen gas into water. The 11 inch diameter sparger consisted of eight fiattened tubular arms capped at the outer ends and joined at the inner ends to a hollow hub and shaft through which oxygen was introduced. Each arm was drilled with eight 1A inch diameter openings equi-spaced between 1.75 and 5.25 inch radii, i.e. the spacings were about 4 center-tocenter diameters apart. With this sparger, the ratio of total cross-sectional area of the openin-gs (and the gas streams injected therefrom into the liquid) to the swept area was 0.01, with 0.83 openings (and gas streams) per square inch of swept area. The sparger was surrounded by an 11% inch inside diameter shroud.

In these tests the speed of rotation of the sparger was varied and the iuid (gas and liquid) ow rates were varied. The sparger (and shroud) was mounted in the bottom of a small cylindrical column connected at top and bottom with an adjacent tank containing water. A pump with means for controlling the discharge rate was provided between the tank and the top of the column whereby the downward ow rate of water through the sparging zone could be regulated and maintained at a desired value. Accordingly, an axial flow impeller was not required or provided for these particular tests. In the interests of demonstrating capability of these devices to produce small bubbles, the plugging problem was ignored andthe circulating liquid wasrclean water uncontaminated with solid particles of appreciable size.A e

Comparative testsv were also conducted with a stationary (non-rotating) sparger. The stationary sparger was provided with sixteen very small 1/32 inch diameter orifices. These orifices were drilled in eight tubular arms of a conguration similar to FIGS. 3-4 having an overall inscribed circle diameter of 11 inches. The arms were 1A diameter tubes with two orifices per arm spaced about 4 4 inches apart. The results of the tests are summarized in Table II.

TABLE II Gas stream tangential velocity,

t./sec. Gas Average l Gas stream Gas lineal bubble Y Test Inner Outer Sparger, ilow, ft/ velocity, N2D, H2O flow, size, Bubble size Bubble f Areal Number No. opening opening Sparger r.p.m. see-it.2 It./see. ttl/sec.2 ft./sec. inches uniformity stability ratio ratio 1 1- 8. 5 25. 4 Rotating... 554. 7 5. 8X10'e 0. 56 69.3 0. 329 0.83 2 9.9 29.6 --..-do.- 647.0 7.7X10 0.75 97.8 0.328 0.83 l0. 1 30.2 do. 657. 0 9 4)(10n 0. 1 100. 8 0.328 0.83 0 Stationary.. 0 0 45.4 0 0.503 0 0 0 0 .---.do 0 0 57.0 0 0.392 --.-.do .-do-..--- 0 0 0 0 ..-.-dO 0 0 36.2 0 0.577 do do 0 0 l Ratio of total cross-sectional area of gas streams to the swept area.

l Number of gas streams per square inch of swept area. bubbles than did the stationary sparger containing smaller 1,(2 inch diameter openings. The bubbles produced by the rotating sparger averaged between t@ and 1A, inch in diameter while those produced by the stationary sparger (Test 6) were 1A; to 1A inch diameter.

It was also observed photographically that bubbles produced by the rotating sparger are very uniform in size compared to those from the stationary sparger. Uniformity is important and desirable particularly for the exclusion of very large bubbles, since only a few such bubbles can account for a significant fraction of the total gas volume. Thus, a small number of over-sized bubbles will materially reduce the bubble population and interfacial area per unit volume of gas in the system.

The improved stability of the small bubbles produced by this invention, even with a very dense population of bubbles, is also quite evident from the data. A review of Tests 1, 2 and 3 show that the small bubbles from the rotating sparger remained discrete and separate despite an increase in gas iiow rate of about 60%. By comparison, the larger bubbles of stationary sparger Tests 4, 5 and 6 showed a strong tendency to coalesce and this tendency was greatly aggravated by increasing the gas rate by about `60%. It should not be concluded from the data of Table II that the use of 1,4;2 inch diameter orifices in the rotating sparger of the present invention is unsatisfactory. lf the stationary sparger provided with 1;@2 inch diameter orifices had been rotated at appropriate velocity, the size of the bubbles produced thereby would have been as small as or smaller than those produced in the 1A; inch orifice tests. The employment of smaller orifices in the stationary tests than in the rotating tests emphasizes the fact that the benefits of the present invention cannot be achieved in a stationary sparger by reducing the oriiice size.

In the aforedescribed tests, eight radial baflies were provided at equal spacings around the shroud circumference in a spoke-like configuration positioned between the shroud wall and a 2-inch inner ring. These bafes were 2 inches long in the longitudinal direction (parallel to the rotating shaft) and were positioned above the sparger to inhibit rotation of the liquid within the shroud. An attempt was made to operate the sparger with the batlies removed. However, it was found that a chimney effect occurred at the center of the column and was caused by a rapidly rising channel of huge bubbles which had coalesced near the center of the sparger. The vertical radial baliies prevent liquid rotation and therefore increase relative tangential velocity Vt at a given sparger r.p.m. (a higher N2D2 factor). Huge bubbles occur when Vt is low, i.e. less than 4.5 f.p.s. (N2D2=2l).

In other tests conducted with the same system and observed by high-speed motion picture film, the speed of rotation of the sparger was progressively increased from zero while maintaining constant iiuid flow rates. The films showed that a minimum tangential velocity of about 4.5 f.p.s. was required at the innermost opening of this particular system in order to produce the desirable cloud of stable, small diameter bubbles in the liquid. At this rotational speed, the tangential velocity of the outermost orifice was about 14 f.p.s. (N2D2=21). At lower velocities the aforedescribed chimney effect was observed with the characteristically huge bubbles.

The ability of the rotating sparger to rapidly dissolve oxygen gas into the liquid was determined directly by measuring the dissolved oxygen in the liquid at the base of the mixing chamber immediately downstream of the sparger with respect to liquid ilow (point l) and at the liquid feed point to the chamber about 5 feet upstream of the sparger (point 2). The results of typical measurements (using data points selected at entering liquid DO levels of about l0, l5, 20 and 30 p.p.m.) are summarized in Table III:

1 Numbers correspond to tests numbers in Table II.

These data show that the instant method may be used to transfer oxygen gas to water. over a wide range of initial DO concentrations.

Dissolved oxygen data was taken which permitted a comparison of the overall effectiveness of the test chamber with the stationary sparger and with the rotating sparger. The following Table IV shows the DO level of water in and out of the chamber and the DO change which occurred. Data is selected for a consistent entering DO level of about l0 p.p.m.

TABLE IV y DO'level, p.p.m.

D0 change,

Test number l Spargel.- In Out p.p.m.

1 Rotating... 10.59 1s. 12 7. 53'

l Numbers correspond to test numbers in Tables II and III.

The Table IV tests show that the rotating sparger transferred at least five times as much oxygen to the liquid as the stationary sparger. It should be noted however that the Table II-IV tests do not represent a quantitative comparison of the invention with the prior art because of the low gas lineal velocities (0.56-,0.91 f.p.s.) and even more importantly the low downward liquid lineal velocity (0.33 f.p.s.). Under these ciricumstances the gas bubbles actually rose through the column of liquid and were not swept downwardly from the lower end of the sparging zone with the liquid. As previously discussed, the high mass transfer rates characteristic of this method require gas lineal velocities of at least 5 f.p.s. into the liquid, and liquid downward lineal velocities of at least 2 f.p.s.

Another series of tests were conducted with the aforedescribed rotating sparger system, except that all gas injection openings on each of the eight radial arms were masked except outermost openings located on a radius of 5.25 inches. This was done in order to eliminate one of the many variables which had been present in previous tests of the rotating sparger. An important objective of these particular tests was to study the eect of tangential gas velocity and rotating speed on bubble diameter, and by placing all openings on the same circle the tangential velocity of all openings was uniform. Vertical radial baffles were employed above and below the rotating sparger.

The apparatus was operated with air at various rotating speeds, hence at sefveral tangential velocities of the air streams, with the character of the gas dispersion in the liquid being recorded photographically. For each condition (r.p.m. or air tangential velocity), a representative group of bubbles were measured, and the size distribution of the bubbles within the group was determined. The results are shown on FIG. 7 for six different values of the factor NZD2 as previously defined. This data is specific for Ms inch diameter openings immersed 5.8 feet below the water surface and for a gas lineal velocity of 12.2 f.p.s. (NTP) through each injection opening. This gas lineal velocity through only 8 orifices provides a gas flow rate of only about 0.011 actual cubic feet of gas per second per square foot of horizontal sparger area. The gas [flow rate is below the 0.06 lower limit specified herein, but the purpose of the instant tests was to study bubble size distribution and not to obtain a high degree of mass transfer eticiency.. The number of bubbles produced was more than adequate to show the size distribution in a statistically accurate manner.

The use of FIG. 7 may be illustrated as follows: at a gas stream relative tangential velocity of 8.7 f.p.s. (N2D2=8.4), at least 90% of all the bubbles within a selected sample will be 0.37 inch diameter or smaller. Similarly, at 11.5 f.p.s. relative tangential velocity (N2D2=14.6) 90% of the bubbles within a selected sample will be smaller than 0.18 inch diameter. The graph is plotted on coordinates wherein the abscissa is a probablility scale, so that a bubble population which lits a normal bell-shaped distribution curve will fall on a straight line. It is seen that at low gas stream tangential velocities increasing from Oto 10.1 f.p.s. (values of N2D2 from to 11.2), bubble distribution is not normal, since inordinately large-size bubles are formed in relatively large numbers. However, a small additional increase in tangential velocity to 11.5 f.p.s. (NZD2 of 14.6) results in a sudden change in the bubble population, whereby smaller bubbles are produced which lit a normal distribution curve.A It appears that the large bubbles occurring at low relative tangential velocity are produced (1) by continued growth at the gas injection opening in the absence of shear forces sufticient to disengage the bubbles from the sparger, (2) by coalescence of adjacent bubbles within the liquid after disengagement occurs, and (3) by the stable assistance of the large lbubbles in the relatively low turbulence level of the liquid in the sparging Vzone.-At the higher velocities, the shear forces are greater and bubble growth at the opening tends to be limited to a bubble diameter not larger than the opening diameter. The smaller bubbles produced at the opening.r and in the high shear-turbulence zone in the wake of the sparger arms are less likely to -coalesce in the liquid.

vFIG. 8 is vbased on the same data as FIG. 7.. The ordinate is the vratio of gas bubble surface area to gas quantity and is therefore an indicator of the gas-to-liquid mass transfer effectiveness. FIG. 8 illustrates the importance of tangential velocity and turbulence to the present invention in a more dramatic manner than FIG. 7. At low values of NZDZ below about 11.2, large unstable bubbles were produced and the surface area of gas created in each cubic foot (NTP) of gas injected into the liquid was about 200 square feet or less at higher values of NZD2 of about 14.6 and above, the small stable bubbles provide a surface area of about 450 square feet and higher for each cubic foot of injected gas. The transition between these two conditions is quite abrupt.

As previously indicated, the FIGS. 7-8 data is based on a single volumetric rate of gas introduction into the sparging zone. Moreover, the liquid downflow rate through the sparging zone was quite low as the objective was to suppress rather than reverse the buoyant upward rise of the bubbles and thereby facilitate close inspection of bubble size. Additional tests were conducted at other volumetric ilow rates of gas into the sparging zone and again it was found that for each gas rate a rather abrupt transition in bubble size occurred in a specific unique range of rotating speeds (or N2D2). It was also observed that as gas sparging rates increased, the rotating speed factor NZD2 required to reach the small, stable bubble regime increased correspondingly.

In yet another series of tests, the volumetric gas ilow rate, the liquid downcliow rate and the sparger rotating speed were vvaried. In some tests, no impeller was employed so that the liquid downilow rate was essentially zero. An impeller was used in other tests, and by substituting impellers of dilerent pitch/diameter ratio, the liquid downow rate was varied independently of the sparger rotating speed. These tests were conducted in a tank 8 by 8 feet crosssection and 9 feet deep lled With water to a depth of 8 feet.

The sparger was provided with eight arms each 11 inches from tip to shaft center and was submerged 6.2 feet -(22 inches from tank bottom). A three-blade marinetype propeller of selected pitch/diameter ratio was installed on a common shaft 11 inches above the plane of the sparger (corresponding to the aforementioned vertical distance between impeller blade and sparger arm horizontal center planes). Each arm of the sparger was provided with twenty-six 1A; inch diameter orifices located along upper and lower surfaces thereof with variable spacing ranging from 1/2 inch center-to-center distance (for outer holes) to l inch (for inner holes). A source of air was provided to the hollow shaft with means to control and measure the flow rate. -Provision was also nacfle to vary and measure the rotating speed of the s a t.

The result of the tests are shown on FIG. 9 which is a graph with NZD2 (ft.2/sec.2) as ordinate and with volumetric gas ow rate (actual cubic feet per second per square foot horizontal area of the sparger zone) as abscissa. The incipient ooding boundaries of the propeller/ sparger at various values of downward liquid velocity V1 are shown as a series of curves on the graph. FIG. 9 shows the limiting value'of liquid downliow V1 which is required for a desired pairing of values of NBD2 and gas flow rate. Thus, if it is desired to introduce 1.6 actual cubic feet gas per second per square foot sparged area using a value of NZD2 of 30, then the liquid downflow rate should not be less than about 3.5 ft./sec.

An important observation during this series of tests was the strong dependence of system performance on the liquid downow rate. As liquid velocity was increased above 2 feet/second the spargers capability to disperse gas into small bubbles increased greatly even though its speed of rotation was held constant. Therefore, the Volumetric gas ow rate of the sparger could be increased to much higher values without necessarily increasing the rotational speed of the sparger. Thus, in addition to the aforementioned relationship between volumetric gas flow rate and N2D2 which permits higher gas tlow rates at higher rotational speeds, the gas capacity can be further increased by increasing the liquid downflow velocity.

Below the value of 2 ft./sec. liquid rate is a regime in which the downward liquid velocity approaches the terminal liquid velocity of the bubbles. The bubbles still cannot escape upwardly by their buoyancy, and the liquid velocity becomes too low to sweep the bubbles downwardly out of the sparging zone as rapidly as they are produced. Total liooding results as the accumulating gas bubbles in the sparging zone coalesce into large pockets of gas which rise into the propeller and the system becomes incapable of producing and dispersing small bubbles. If liquid velocity is still further diminished below the terminal velocity, a steady state small bubble regime again appears at low volumetric gasow rates, butsuch gas rates are far below 0.06 actual cubic feet per second per square foot horizontal area of the sparging zone and too low for practical usage. The region of operability according to the method of this invention may be identied on the FIG. 9 graph. The vertical dotted line for gas flow rate (g)==0.06 ft.3/sec. x ft? is the minimum value of this parameter for achieving an effective balance of mass transfer and power consumption. The incipient flooding curve V1=2 also represents a lower limit on liquid lineal velocity needed to achieve high mass transfer rates (K13) and to effectively disperse the gas bubbles from the sparging zone. Also, the horizontal lines for the factor N2D2=15 is the lower limit for acceptably high mass transfer rates.

It will be understood by those skilled in the art that despite the coupling of the impeller and sparger to a common shaft, the liquid pumping rate of the impeller can be varied independently of the rotational speed by changing the pitch/diameter ratio of the impeller. On preferred practice of this invention the pitch/diameter ratio of the impeller is at least 1.5. It has been observed that by changing the pitch/diameter ratio from 1.0 to 1.5 and holding the factor N2D3 constant, the gas rate can be increased over 50% and the mass transfer rate over 75%.

Although the aforedescribed tests related to sparging systems employing to 1A inch diameter gas injection openings, the general relationships set forth are believed applicable to 176,2 inch openings and such may be used in the practice of this invention. Openings smaller than )Q2 inch diameter are subject to clogging where the liquid contains solid materials. It also appears that saturation of the gas (to be injected in the liquid as a multiplicity of streams) becomes more important as the opening diameter and gas stream diameter is reduced, so as to avoid evaporation and solids disposition in the openings. Openings larger than 1A inch do not provide the small bubble necessary for the high gas-liquid interfacial surface area/volume ratio characteristic of this invention. This is illustrated by Table V which is based on the approximation that at stable operation, the mean bubble diameter is about the same as the gas injection opening diameter. It should be recognized however that several other factors could influence the relationship between opening diameter and stability of operation, such as hydrostatic head and gas injection opening profile.

Still another series of tests were conducted with large scale equipment schematically illustrated in FIGS. 12. Tank had 2700 gallons liquid capacity and was 7 feet in diameter. Whereas liquid was recirculated in the desired llow path of an external pump in the small scale tests, in the large scale tests propeller 4 -was mounted on hollow shaft 2 above eight-arm sparger 2 also mounted on this shaft. The latter was powered by motor 7 (3%4 HP direct current type). During certain of these tests vertical radial baliies 12 were attached to the tank wall 'at 90 intervals, and various other vertical radial bales 9a- 9c were provided around the propeller-Spargel"l assembly, also at 90 intervals.

Some tests employed an 18 inch diameter, 1'8 inch pitch propeller while others used an 18 inch diameter, 27 inch pitch propeller. Several sparger embodiments were employed, all consisting of eight radial arms in an enscribed circle, 18 inches in diameter. These arms were fabricated of 5/16 inch OJD. tubing which was flattened to about /m inch width along the portion of the length containing the openings to provide a substantially flat configuration with a major axis Am of 0.25 inch and minor axis Am, of 0.06 inch. One design used straight arms, each containing twelve 1A; inch diameter orifices spaced 1/2 inch apart (four diameters) in the top of the arms beginning 1A inch from the arm tip (ninety-six total openings). The ratio of total cross-sectional area of openings and gas streams to the swept area was 0.018 with 1.46 openings and gas streams per square inch of swept area. This sparger was tested with the openings facing upward, facing downward, and facing at an acute angle to the vertical. In other tests, the above sparger was modified by drilling the holes completely through the tube arms, thus providing ninety-six openings on the top and ninety-six on the bottom (one hundred ninety-two total openings). In still other tests, the number of openings was again doubled by drilling additional l/s inch diameter holes through the tube arms midway between the existing openings (three hundred eighty-four total openings). Yet another sparger containing one hundred ninety-two openings was tested using arms curved in the horizontal plane on a radius of about 151/2 inches. l

In some tests, the full array of narrow radial baffles 9a-c were employed. In other tests, only the bottom narrow batlles 9a was retained, while in still others allr narrow radial bafes were removed but in all tests the long baies 12 were employed.

During these tests, it was determined that outstanding performance (in terms of transferring gas as small bubbles to liquid through 1A; inch diameter openings) can be obtained whether the openings are provided in the top, bottom, or both sides of the sparger arms. However, in all of these configurations, the center axis of the opening had a vertical direction component and the gas streams were injected in a direction having a vertical component. It was also determined that narrow straightening bafes 9a-c are not required to avoid vortex formation in larger tanks Where the mass of liquid being circulated (for sweeping the gas bubbles away from the sparging zone) is smallin relation to the mass of the total liquid body. However,` long radial baffles 12 were employed and the apparatus of this invention requires some type of vertical radial bales at spaced intervals around the lower end of the rotatable shaft.

tAlthough preferred embodiments of this invention have been described in detail, it is contemplated that modifications of the method and apparatus may be made and that some features may be employed without others, all within the spirit and scope of the invention. For example, the gas injection openings in the sparging arms need not be provided in a single longitudinal row but may instead be provided in multiple. i

In this event, the requirement of center-to-center spacings at least 2 diameters refers to any pair of adjacent openings whether they be in the same or different rows.

' What is claimed is:

1. A method for sparging gas into liquid comprising the steps of injecting into liquida multiplicity of discrete gas streams of V32-1A inch effective diameter at lineal velocity of at least 5 feet per second and at volumetric ow rate of at least 0.06 actual cubic feet per second per square foot of horizontal area in a sparging zone as gas bubbles in direction having at least a vertical component, and simultaneously orbiting said gas streams at tangential velocity of 4.5-33 feet per second and at rate such that the factor NPID2 is at least 15 feet2 per second2 about a common vertical axis so as to scribe a multiplicity of circles each perpendicular to said vertical axis but at dilerent radii with all such circles when projected on the horizontal plane falling within a swept area bounded by the circles of minimum and maximum radii, the ratio of total cross-sectional area of said gas streams to said swept area being 0.006-006; ilowing said liquid at lineal velocity of at least 2 feet per second downwardly through said sparging zone for gas injection therein; and discharging the downwardly owing gas bubble-containing liquid from the lower end of said sparging zone.

2. A method according to claim 1 wherein the gas streams are 1A; inch diameter.

3. A method according to claim 1 wherein the lineal velocity of the liquid is 3-7 feet per second.

4. A method according to claim 1 wherein the gas streams are 1A; inch diameter, the ratio of total crosssectional area of said gas streams to the swept area of said rotating locations is (LOGS-0.04, with 1-4 gas streams per square inch of swept area.

5. A method according to claim 1 in which the gas streams are injected into liquid at volumetric flow rate of at least 0.10 actual cubic feet per second per square foot of horizontal area.

6. A method according to claim 1 in which said gas streams orbit around said common vertical axis in the same plane of rotation.

7. A method according to claim 1 in which the factor N2D2 is at least 20 feet2 per second2.

8. A method for sparging oxygen into waste liquor containing organic solids, comprising the steps of injecting into waste liquor a multiplicity of discrete oxygen gas streams of 1A; inch diameter spaced at 2.5-3.5 center-tocenter diameters apart at lineal velocity of at least 5 feet per second and at volumetric flow rate of at least 0.10 actual cubic feet per second per square foot of horizontal area in a sparging zone as oxygen gas bubbles in the vertical direction, and simultaneously orbiting said oxygen gas streams at tangential velocity of 4.5-33 feet per second and at rate such that the factor N2D2 is at least 20 feet2 per second2 about a common vertical axis so as to scribe a multiplicity of circles each perpendicular to said vertical axis but at different radii with all such circles in a horizontal plane falling within a swept area bounded by the circles of minimum and maximum radii, the ratio of total cross-sectional area of said oxygen gas streams to said swept area being (LOGS-0.04 with 1-4 oxygen gas streams per square inch of swept area; owing said waste liquor at lineal velocity of 3-7 feet per second downwardly through said sparging zone for oxygen gas injection therein; and discharging the downwardly owing oxygen gas bubble-containing waste liquor from the lower end of said sparging zone.

9. Apparatus for sparging gas into liquid comprising:

'(a) pressurized gas supply means;

(b) a vertically oriented rotatable shaft having a passageway therein joined at its upper end to said gas supply means;

(c) an axial :How impeller xedly attached to said rotatable shaft with outwardly extending blades intermediate said upper end and the shaft lower end aligned to ow liquid downwardly;

(d) a multiplicity of gas sparging arms dixedly attached to said rotatable shaft as its lower end, each extending radially outwardly from and spaced around the shaft with the diameter scribed by the arm tips 0.8- 1.1 times the diameter scribed by the impeller blade tips and each arm having an interior passageway communicating with the rotatable shaft passageway, and a multiplicity of :V32-1A inch effective diameter openings spaced from each other along the arm length with the center axis of said openings having a vertical direction component so as to scribe a multiplicity of circles each perpendicular to said rotatable shaft but at diiferent radii with all such circles when projected on the horizontal plane falling within a swept area bounded by the circles of minimum and maximum radii, said openings being provided in suicient size and number such that the ratio of total cross-sectional area of said openings to said swept area is 0.006-006; and

(e) a multiplicity of vertical radial batlies at spaced intervals around the lower end of said rotatable shaft.

10. Apparatus according to claim 9 in which the horizontal center plane of said sparging arms is positioned no more than a distance equal to the impeller blade tip scribed diameter beneath the impeller horizontal center plane. 11. Apparatus according to claim 9 in which the diameter scribed by the sparging arm tips is 0.9-1.1 times the diameter scribed by the impeller blade tips and the horizontal center plane of said sparging arms is positioned no more than a distance equal to one-half the impeller blade tip scribed diameter beneath the impeller horizontal center plane.

12. Apparatus according to claim 9 in which the sparger arms are of substantially flat cross-section with a major axis normal to said center axis of the gas injection openings and at least twice the length of a minor axis parallel to such openings.

13. Apparatus according to claim 9 in which the sparger arms are in the same plane of rotation and attached to said rotatable shaft at the same elevation.

14. Apparatus according to claim 9 with 0.125-20 openings in the sparging arms per square inch of swept area.

15. Apparatus according to claim 9 in which said openings are provided in suicient size and number such that the ratio of total cross-sectional area of said openings to said swept area is 0008-004 with 1-4 openings per square inch of swept area.

16. Apparatus according to claim 9 with said blades of the impeller having a pitch/ diameter ratio of at least 1.5.

References Cited UNITED STATES PATENTS 2,041,184 5/ 1936 Isenhour 261-87 X 1,124,855 1/1915 Callow et al. 261-87 2,928,661 3/ 1960 MaCLaren 261-87 X MICHAEL ROGERS, Primary Examiner U.S. Cl. X.R. 

